An organic solvent-free microwave-assisted extraction of some priority pollutants of phenols in lake sediments.

نویسندگان

  • Linling Wang
  • Weihong Huang
  • Xiumei Shao
  • Xiaohua Lu
چکیده

Alkaline water was used for the microwave-assisted extraction of some priority pollutants of phenols in sediments, i.e. phenol (Ph), 2-chlorophenol (2CP), 2,4-dichlorophenol (2,4DCP), 4-chlorophenol (4CP), 4-dinitrophenol (4NP) and pentachlorophenol (PCP). This organic solvent-free extraction procedure was optimized by studying the parameters such as pH, volume of the alkaline water, extraction pressure and time. Under the optimized conditions, the recoveries of phenols were in the range of 80% to 110%. The extracts were then cleaned-up and concentrated by microcolumn solid phase extraction (SPE) and determined by gas chromatography-flame ionization detection system. The relative standard deviation of the overall-method for most phenol determinations was about 5.0% (n = 6). The proposed method, which needs little volume (1 mL) of ethanol for SPE, has been applied to determine these phenols in sediment samples, and the analytical results are in good agreement with those achieved by Soxhlet extraction.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Methodologies for the extraction of phenolic compounds from environmental samples: new approaches.

Phenolic derivatives are among the most important contaminants present in the environment. These compounds are used in several industrial processes to manufacture chemicals such as pesticides, explosives, drugs and dyes. They also are used in the bleaching process of paper manufacturing. Apart from these sources, phenolic compounds have substantial applications in agriculture as herbicides, ins...

متن کامل

Microwave-assisted Synthesis of Nـ alkyl 2ـ ketomethyl quinoline Derivatives Under Solvent-free Conditions

A series of Nـ alkyl 2ـ ketomethylquinoline derivatives were synthesis by reaction of benzoyl chloride derivatives with Nـ methyl quinaldine iodide in the presence of triethyl amine under microwave irradiation. Enaminone form of the product study by spectroscopy method. The result revealed the  Nـ alkyl 2ـ ketomethylquinoline the fixed enaminone tautomer.

متن کامل

Chemical Composition and Antibacterial Activity of the Essential Oil of Lavandula angustifolia Isolated by Solvent Free Microwave Assisted Extraction and Hydrodistillation

ABSTRACT: Chemical composition of Lavandula angustifolia was studied by solvent free microwave extraction (SFME) and hydrodistillation (HD) methods. 1, 8-cineole (42.7% and 37.9%), Camphor (26.1% and 21.3%) and Borneol (31.2% and 21.6%) were the major compounds that obtained by SFME and hydrodistillation, respectively. The antibacterial activity of extracted oils was investigated against Gram-p...

متن کامل

Comparison of Hydrodistillation, Microwave Hydrodistillation and Solvent Free Microwave Methods in Analysis of the Essential Oils from Aerial Parts of Haplophyllum Robustum Bge. by GC/MS Method

The genus Haplophyllum, which belongs to the Rutaceae family, includes 18 species in Iran. In this study, after collecting plant material, botanical identification and suitable drying, the essential oils from aerial parts of Haplophyllum robustum Bge. were extracted by three different isolation techniques, conventional hydrodistillation (HD), microwave-assisted hydrodistillati...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

دوره 19 11  شماره 

صفحات  -

تاریخ انتشار 2003